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81.
82.
83.
This article presents a simple, low-cost method of fabrication and the applications of flexible polystyrene microfluidic devices with three-dimensional (3D) interconnected microporous walls based on treatment using a solvent/non-solvent mixture at room temperature. The complete fabrication process from device design concept to working device can be completed in less than an hour in a regular laboratory setting, without the need for expensive equipment. Microfluidic devices were used to demonstrate gas generation and absorption reactions by acidifying water with carbon dioxide (CO(2)) gas. By selectively treating the microporous structures with oxygen plasma, acidification of water by acetic acid (distilled white vinegar) perfusion was also demonstrated with the same device design. 相似文献
84.
Dr. Jia Wang Dr. Yong Chen Dr. Yuen‐Chi Law Meiyi Li Dr. Ming‐Xin Zhu Dr. Wei Lu Dr. Stephen Sin‐Yin Chui Dr. Nianyong Zhu Prof. Dr. Chi‐Ming Che 《化学:亚洲杂志》2011,6(11):3011-3019
A series of phosphorescent terpyridyl platinum(II) complexes with ancillary biphenylacetylide ligands, namely, [(R3tpy)PtC≡C(biphenyl)]X (R=tBu, H, or Et2N; tpy=2,2′;6′,2′′‐terpyridyl; X is an anion) were synthesized and structurally characterized by various spectroscopic techniques and X‐ray diffraction methods. Despite a lack of long alkyl chain(s) or hydrogen‐bonding motif(s), complexes [(tpy)PtC≡C(biphenyl)]Cl and [(tBu3tpy)PtC≡C(biphenyl)]X (X=Cl, ClO4, PF6, or BF4) were found to gelate water and organic solvents, respectively. The self‐aggregation of these complexes in solutions and the resulting gels were investigated with variable‐temperature (VT) 1H NMR spectroscopy, polarized optical microscopy, and absorption/emission spectroscopy. SEM micrographs on dry gels revealed entangled nanofibers with diameters of 20–40 nm and lengths of tens of micrometers. Powder X‐ray diffraction (PXRD) study revealed various degrees of crystallinity of these fibrillar nanostructures. The substituents on both the terpyridyl and acetylide ligands and counterion of these complexes play a profound but concerted role in tuning the intermolecular metal???metal and/or π–π interactions, and hence the gelation properties. 相似文献
85.
C. Poor D. S. Yuen 《Abhandlungen aus dem Mathematischen Seminar der Universit?t Hamburg》2005,75(1):51-75
For a Siegel modular cusp formf of weightk letv(f) be the closure of the convex ray hull of the support of the Fourier series inside the cone of semidefinite forms. We show
the existence of the extreme core,C
ext, which satisfiesv(f) ⊇k Cext for all cusp forms. This is a generalization of the Valence Inequality to Siegel modular cusp forms. We give estimations
of the extreme core for general n. For n ≤5 we use noble forms to improve these estimates. Forn = 2 we almost specify the extreme core but fall short. We supply improved estimates for all relevant constants and show optimality
in some cases. The techniques are mainly from the geometry of numbers but we also use IGUSA’s generators for the ring of Siegel
modular forms in degree two. 相似文献
86.
Jason Glenn Christopher K. Walker Erick T. Young 《International Journal of Infrared and Millimeter Waves》1997,18(2):285-300
We present the design of a broad band, 1.3 mm polarimeter for astronomical observations and the results of first light observations
at the Heinrich Hertz Telescope (HHT). The systematic polarization of the instrument plus telescope is 1.1%. The observed
linear polarization of DR 21,P=1.65%±0.14% andθ=16°±2°, is consistent with previous measurements. Our 0.9% upper limit on the linear polarization of Cepheus A is the first
1.3 mm measurement reported. With Cyclops it is possible to map the magnetic fields in several of the brightest molecular
cloud dust cores in the Milky Way. We comment on the expected performance of an achromatic Rexolite half-waveplate for λ=800μm to 1.3 mm. 相似文献
87.
Kun‐Li Wang Tseung‐Yuen Tseng Hung‐Lung Tsai Sheng‐Chieh Wu 《Journal of polymer science. Part A, Polymer chemistry》2008,46(20):6861-6871
A series of poly(aryl ether)s were successfully prepared via aromatic nucleophilic substitution reaction from various bisphenols and a novel bipolar aryl difluoride monomer containing electron‐donor triphenylamine and electron‐acceptor 1,2,4‐triazole moieties. The poly(aryl ether)s exhibited excellent solubility in organic solvents such as dimethylformamide, chloroform, and tetrahydrofuran at room temperature. The poly(aryl ether)s showed high thermal stability with Td10 higher than 500 °C and glass transition temperatures (Tg) higher than 187 °C. The thin films of the poly(aryl ether)s indicated bistable resistive switching behavior with ON/OFF current ratios as high as 103. The switching on and switching off bias voltages of the poly(aryl ether)s were affected by the bisphenol moiety. The good resistive switching behavior of the poly(aryl ether)s made them promising candidates for future nonvolatile memory applications. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 6861–6871, 2008 相似文献
88.
A. Miller D. A. B. Miller M. Bensoussan J. M. Moison D. C. Haueisen D. A. Depatie P. W. Kruse M. A. Khan A. L. Smirl B. S. Wherrett T. F. Boggess G. P. Perryman D. S. Chemla P. W. Smith A. C. Gossard W. T. Tsang S. Chu P. Hu T. M. Jedju S. Y. Yuen P. A. Wolff V. Moloney F. A. Hopf H. M. Gibbs S. L. McCall D. L. Kaplan S. Ovadia J. V. Moloney D. F. Walls 《Applied physics. B, Lasers and optics》1982,28(2-3):92-101
89.
Power efficiencies for five elements have been measured for the helium-oxygen-acetylene and air-acetylene flames. The increased power efficiencies found in this study for the helium-diluted flame, coupled with its enhanced atom-formation capabilities, suggest that lower atomic fluorescence detection limits should exist. However, in a comparison study with an air-acetylene flame using identical experimental conditions, a decreased atomic fluorescence signal-to-noise ratio was found for most elements in the helium-diluted flame. This decrease is ascribed to greater background emission noise in the hotter helium-diluted flame and decreased nebulization efficiency caused by the low density of the helium-containing nebulizer gas. A comparison of flame emission detection limits for the two flames confirms the increased sensitivity of the hotter helium-oxygen-acetylene flame, despite its lower nebulization efficiency. 相似文献
90.
The energy-momentum tensor in spontaneously broken non-Abelian gauge field theories is studied. The motivation is to show that recent results on the finiteness and gauge independence of S-matrix elements in gauge theories extends to observable amplitudes for transitions in a gravitational field. Path integral methods and dimensional regularization are used throughout. Green's functions Γμν(j)(q; p1,…,pj) involving the energy-momentum tensor and j particle fields are proved finite to all orders in perturbation theory to zero and first order in q, and finite to one loop order for general q. Amputated Green's functions of the energy momentum tensor are proved to be gauge independent on mass shell. 相似文献